Agricultural wastes are readily available in farming communities and can be utilised for off-grid electrification as an alternative to diesel generators. This work evaluates for the first time the life cycle environmental sustainability of these small-scale systems in the context of Southeast Asia. Rice and coconut residues are considered for direct combustion and gasification, and livestock manure for anaerobic digestion. Overall, anaerobic digestion is the best option for 14 out of 18 impacts estimated through life cycle assessment.