Photooxidation

Tire materials are a significant proportion of the (micro)plastics in the environment that until today have been clearly overlooked. These materials are released into the environment, either unintentionally as an abrasion product from tire wear, that reaches the environment via road runoff, or intentionally as, for example, shredded “tire crumble rubber” used as filling material for playgrounds.
Elsevier, TrAC - Trends in Analytical Chemistry, Volume 112, March 2019
Plastics are a frequently observed component of marine debris and there is growing concern about microplastic (MP) ecotoxicity, and the impacts of additives, sorbed hazardous organic contaminants, heavy metals, and biofilm on MP surfaces. The relative importance of MP from different terrestrial and freshwater sources is poorly understood and limits our ability to develop best management practices. This review focuses on evidence and methods for source apportionment of MP in freshwater environments including the use of MP characteristics, mass balance techniques, and surface characteristics.